You should make sure not to over-focus on isolation techniques and instead make sure to do full-body workouts that will help you strengthen your whole body. It can be unhealthy to promote certain muscles over others, and you may not see the result you really want that way anyway. Bear in mind also that workout plans that really stress supplements are make claims of the fat-burning benefits of these exercises should be treated with extreme skepticism. If you want to burn fat, you will need to look at your diet and prepare for a lot of cardio, not focus on muscle-building specifically.
Make sure to talk with a professional personal trainer and do your research ahead of time, regardless of what your goals are.